Report your bugs here - if someone else has already mentioned the same bug, just add on to their post with as much info as possible to make the hunting easier.
The sort order is as follows: English articles (a, an, the) are automatically ignored when sorting so "The Hunt" will be sorted under "H". Non-English articles are ignored by default but if you'd like the program to take them into account you can turn on that option in the Preferences > General.
If you want total control over the title sort, use the 'Sort Title' field to tell the program exactly where you'd like a particular movie sorted. By default that field is not turned on but you can do so in the Preferences > General > Fields. Then enter as little as or as much information as you'd like into the field (just a letter or the full title) and the program will use that as guidance for sorting instead.